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Gold Thione Complexes
Caddeo, Francesco
;
Fernández-Moreira, Vanesa
(Universidad de Zaragoza)
;
Arca, Massimiliano
;
Laguna, Antonio
(Universidad de Zaragoza)
;
Lippolis, Vito
;
Gimeno, M.C.
(Universidad de Zaragoza)
Resumen:
The reaction of the ligand Et4todit (4,5,6,7-Tetrathiocino-[1,2-b:3,4-b']-diimidazolyl-1,3,8,10-tetraethyl-2,9-dithione) with gold complexes leads to the dinuclear gold(I) complexes [{Au(C6F5)}2(Et4todit)] and [Au(Et4todit)]2(OTf)2, which do not contain any gold-gold interactions, or to the gold(III) derivative [{Au(C6F5)3}2(Et4todit)]. The cristal structures have been established by X-ray diffraction studies and show that the gold centers coordinate to the sulfur atoms of the imidazoline-2-thione groups.
Idioma:
Inglés
DOI:
10.3390/inorganics2030424
Año:
2014
Publicado en:
Inorganics
2, 3 (2014), 424-432
ISSN:
2304-6740
Financiación:
info:eu-repo/grantAgreement/ES/DGA-FSE/E77
Financiación:
info:eu-repo/grantAgreement/ES/MINECO-FEDER/CTQ2013-48635-C2-1-P
Tipo y forma:
Article (Published version)
Área (Departamento):
Área Química Inorgánica
(
Dpto. Química Inorgánica
)
Área (Departamento):
Proy. investigación HWA
(
Dpto. Química Inorgánica
)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use.
Exportado de SIDERAL (2019-02-22-10:22:56)
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Record created 2017-03-14, last modified 2019-02-22
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