000071029 001__ 71029
000071029 005__ 20201216081413.0
000071029 0247_ $$2doi$$a10.1016/j.saa.2016.06.037
000071029 0248_ $$2sideral$$a97093
000071029 037__ $$aART-2017-97093
000071029 041__ $$aeng
000071029 100__ $$aRamos Silva, M.
000071029 245__ $$aSynthesis, structure and physical properties of a low dimensional compound
000071029 260__ $$c2017
000071029 5060_ $$aAccess copy available to the general public$$fUnrestricted
000071029 5203_ $$aThe crystal structure of (µ3-oxo)hexakis(cyanoacetato-¿O, O')(cyanoacetato-¿O)diaquatriiron(III) cyanoacetic acid shows the formation of trinuclear complexes in a hydrogen-bond network that bonds all the molecules in a 3D arrangement. For this complex, within whose clusters the whole magnetic interaction takes place, 57Fe Mössbauer spectroscopy shows that the Fe cations are in the S = 5/2 state in the temperature range 2–295 K. The asymmetric broadening of the absorption peaks below 80 K is consistent with strong antiferromagnetic interactions between the metal spins. The magnetization measurements also show the antiferromagnetic character of the spin ensemble and an ST = 1/2 magnetic ground state typical of triangular systems with similar J between Fe-Fe pairs.
000071029 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000071029 590__ $$a2.88$$b2017
000071029 591__ $$aSPECTROSCOPY$$b7 / 42 = 0.167$$c2017$$dQ1$$eT1
000071029 592__ $$a0.648$$b2017
000071029 593__ $$aInstrumentation$$c2017$$dQ1
000071029 593__ $$aSpectroscopy$$c2017$$dQ2
000071029 593__ $$aAnalytical Chemistry$$c2017$$dQ2
000071029 593__ $$aAtomic and Molecular Physics, and Optics$$c2017$$dQ2
000071029 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000071029 700__ $$aCoutinho, J. T.
000071029 700__ $$aPereira, L. C. J.
000071029 700__ $$0(orcid)0000-0003-2713-2786$$aMartín-Ramos, P.$$uUniversidad de Zaragoza
000071029 700__ $$aWaerenborgh, J. C.
000071029 7102_ $$15011$$2500$$aUniversidad de Zaragoza$$bDpto. CC.Agrar.y Medio Natural$$cArea Ingeniería Agroforestal
000071029 773__ $$g172 (2017), 9-13$$pSpectrochim. acta, Part A: Mol. biomol. spectrosc.$$tSPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY$$x1386-1425
000071029 8564_ $$s472665$$uhttps://zaguan.unizar.es/record/71029/files/texto_completo.pdf$$yPostprint
000071029 8564_ $$s98612$$uhttps://zaguan.unizar.es/record/71029/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
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000071029 951__ $$a2020-12-16-08:09:47
000071029 980__ $$aARTICLE