000065582 001__ 65582
000065582 005__ 20200113145614.0
000065582 0247_ $$2doi$$a10.1515/chem-2018-0007
000065582 0248_ $$2sideral$$a104370
000065582 037__ $$aART-2018-104370
000065582 041__ $$aeng
000065582 100__ $$aFayos, O
000065582 245__ $$aSynthesis of (±)-3,4-dimethoxybenzyl- 4-methyloctanoate as a novel internal standard for capsinoid determination by HPLC-ESI-MS/MS(QTOF)
000065582 260__ $$c2018
000065582 5060_ $$aAccess copy available to the general public$$fUnrestricted
000065582 5203_ $$aCapsinoids exhibit health-promoting properties and are therefore compounds of interest for medical and food sciences. They are minor compounds present in relatively high concentrations in only a few number of pepper cultivars. It is desirable to quantify capsinoids to provide selected cultivars with high capsinoid contents, which can then be employed as health food product. Quantifying low concentrations of capsinoids from pepper fruit requires a precise and selective analytical technique such as HPLC coupled to electrospray ionization - mass spectrometry, with development of an internal standard essential. In this work, the synthesis method of a novel compound analogue of capsinoids, the (±)-3,4-dimethoxybenzyl-4-methyloctanoate, which could be a suitable internal standard for capsinoid determination by electrospray ionization - mass spectrometry is described.
(±)-3,4-dimethoxybenzyl-4-methyloctanoate was stable under the analysis conditions and exerted chemical and physical properties similar to those of capsinoids. This internal standard will provide an accurate capsinoid determination by electrospray ionization - mass spectrometry, thus facilitating the pepper breeding programs, screening pepper cultivars and a better understanding of capsinoid biosynthetic pathway.
000065582 536__ $$9info:eu-repo/grantAgreement/ES/INIA/RTA2015-00042-C02-00$$9info:eu-repo/grantAgreement/ES/INIA-FEDER/RTA2011-00118-C02-01
000065582 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000065582 590__ $$a1.512$$b2018
000065582 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b111 / 172 = 0.645$$c2018$$dQ3$$eT2
000065582 592__ $$a0.345$$b2018
000065582 593__ $$aMaterials Chemistry$$c2018$$dQ2
000065582 593__ $$aChemistry (miscellaneous)$$c2018$$dQ2
000065582 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000065582 700__ $$aBarbero, GF
000065582 700__ $$0(orcid)0000-0001-7299-0187$$aSavirón, M
000065582 700__ $$0(orcid)0000-0003-3514-2570$$aOrduna, J$$uUniversidad de Zaragoza
000065582 700__ $$aDurán, AG
000065582 700__ $$aPalma, M
000065582 700__ $$aMolinillo, JMG
000065582 700__ $$aMacías, FA
000065582 700__ $$aBarroso, CG
000065582 700__ $$aMallor, C
000065582 700__ $$0(orcid)0000-0002-6727-5928$$aGarcés-Claver,A$$uUniversidad de Zaragoza
000065582 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica
000065582 7102_ $$15011$$2705$$aUniversidad de Zaragoza$$bDpto. CC.Agrar.y Medio Natural$$cÁrea Producción Vegetal
000065582 773__ $$g16, 1 (2018), 87-94$$pOpen Chem.$$tOpen Chemistry$$x2391-5420
000065582 8564_ $$s1219485$$uhttps://zaguan.unizar.es/record/65582/files/texto_completo.pdf$$yVersión publicada
000065582 8564_ $$s127240$$uhttps://zaguan.unizar.es/record/65582/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000065582 909CO $$ooai:zaguan.unizar.es:65582$$particulos$$pdriver
000065582 951__ $$a2020-01-13-14:52:31
000065582 980__ $$aARTICLE