Experimental and Theoretical Studies on the Structure and Photoluminescent Properties of New Mononuclear and Homodinuclear Europium(III) ß-Diketonate Complexes
Resumen: Two novel europium(III) complexes, a monomer and a homodimer, with 1-(4-chlorophenyl)-4,4,4-trifluoro-1,3-butanedione (Hcbtfa) and 5-chloro-1,10-phenanthroline (cphen) ligands, formulated as [Eu(cbtfa)3(cphen)] and [Eu2(cbtfa)4(cphen)2(CH3O)2], have been synthesized. Their structures have been elucidated by X-ray diffraction and their absorption and emission properties have been studied in the solid state. The experimental data has then been used to test the recently released LUMPAC software, a promising tool which can facilitate the design of more efficient lanthanide light-conversion molecular devices by combining ground state geometry, excited state energy, and luminescent properties calculations.
Idioma: Inglés
DOI: 10.1155/2015/205047
Año: 2015
Publicado en: ADVANCES IN CONDENSED MATTER PHYSICS 2015 (2015), 205047 [12 pp]
ISSN: 1687-8108

Factor impacto JCR: 0.932 (2015)
Categ. JCR: PHYSICS, CONDENSED MATTER rank: 51 / 67 = 0.761 (2015) - Q4 - T3
Factor impacto SCIMAGO: 0.312 - Condensed Matter Physics (Q3)

Tipo y forma: Article (Published version)
Área (Departamento): Area Ingeniería Agroforestal (Dpto. CC.Agrar.y Medio Natural)

Creative Commons You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use.


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