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000063471 037__ $$aART-2015-103194
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000063471 100__ $$aIglesias, Manuel
000063471 245__ $$aMecanismos de Esfera Externa en Reacciones de Hidrosililación Catalítica
000063471 260__ $$c2015
000063471 5060_ $$aAccess copy available to the general public$$fUnrestricted
000063471 5203_ $$aRecent reports on homogeneous catalytic hydrosilylation suggest that this reac- tion may not always operate by the generally accepted classical catalytic cycles. Ionic and concerted outer-sphere mechanisms are broadly accepted in hydrogenation catalysis; however, they have been barely reported for catalytic hydrosilylation. Mechanistic studies hint at the heterolytic splitting of Si–H bonds as initial step of the non-classical catalytic cycle.
000063471 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/Consolider-Ingenio/CTQ2011-27593$$9info:eu-repo/grantAgreement/ES/MINECO/Consolider-Ingenio/CSD2009-0050
000063471 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc$$uhttp://creativecommons.org/licenses/by-nc/3.0/es/
000063471 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000063471 773__ $$g70 (2015), 39–57$$pRev. Acad. Cienc. Exactas, Fís.-Quím. Nat. Zaragoza$$tRevista de la Academia de Ciencias Exactas, Físico-Químicas y Naturales de Zaragoza$$x0370-3207
000063471 8564_ $$s864194$$uhttps://zaguan.unizar.es/record/63471/files/texto_completo.pdf$$yVersión publicada
000063471 8564_ $$s67538$$uhttps://zaguan.unizar.es/record/63471/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
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000063471 951__ $$a2017-12-13-12:08:23
000063471 980__ $$aARTICLE