Resumen: The regioselective double hydrophosphination of alkynes mediated by rhodium catalysts is presented. The distinctive stereoelectronic properties of the NHC ligand prevent the catalyst deactivation by diphosphine coordination thereby allowing for the closing of a productive catalytic cycle.
Idioma: Inglés
DOI: 10.1039/c5cc09156j
Año: 2016
Publicado en: CHEMICAL COMMUNICATIONS 52, 32 (2016), 5554-5557
ISSN: 1359-7345

Factor impacto JCR: 6.319 (2016)
Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 23 / 166 = 0.139 (2016) - Q1 - T1
Factor impacto SCIMAGO: 2.537 - Catalysis (Q1) - Ceramics and Composites (Q1) - Chemistry (miscellaneous) (Q1) - Surfaces, Coatings and Films (Q1) - Materials Chemistry (Q1) - Metals and Alloys (Q1) - Electronic, Optical and Magnetic Materials (Q1)

Financiación: info:eu-repo/grantAgreement/ES/DGA/E07
Financiación: info:eu-repo/grantAgreement/ES/MICINN-FEDER/CSD2009-00050
Financiación: info:eu-repo/grantAgreement/ES/MINECO/CTQ2013-42532-P
Tipo y forma: Congress (PostPrint)
Área (Departamento): Área Química Inorgánica (Dpto. Química Inorgánica)

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