000061286 001__ 61286
000061286 005__ 20210930085401.0
000061286 0247_ $$2doi$$a10.3762/bjoc.13.59
000061286 0248_ $$2sideral$$a98646
000061286 037__ $$aART-2017-98646
000061286 041__ $$aeng
000061286 100__ $$aCastán, A.
000061286 245__ $$aSynthesis of new pyrrolidine-based organocatalysts and study of their use in the asymmetric Michael addition of aldehydes to nitroolefins
000061286 260__ $$c2017
000061286 5060_ $$aAccess copy available to the general public$$fUnrestricted
000061286 5203_ $$aNew pyrrolidine-based organocatalysts with a bulky substituent at C2 were synthesized from chiral imines derived from (R)-glyceraldehyde acetonide by diastereoselective allylation followed by a sequential hydrozirconation/iodination reaction. The new compounds were found to be effective organocatalysts for the Michael addition of aldehydes to nitroolefins and enantioselectivities up to 85% ee were achieved.
000061286 536__ $$9info:eu-repo/grantAgreement/ES/DGA/GAE-102
000061286 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000061286 590__ $$a2.33$$b2017
000061286 591__ $$aCHEMISTRY, ORGANIC$$b25 / 57 = 0.439$$c2017$$dQ2$$eT2
000061286 592__ $$a0.929$$b2017
000061286 593__ $$aOrganic Chemistry$$c2017$$dQ1
000061286 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000061286 700__ $$0(orcid)0000-0002-5554-3040$$aBadorrey, R.$$uUniversidad de Zaragoza
000061286 700__ $$0(orcid)0000-0002-4972-7476$$aGálvez, J.A.$$uUniversidad de Zaragoza
000061286 700__ $$0(orcid)0000-0001-9033-8459$$aDíaz de Villegas, M.D.
000061286 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica
000061286 773__ $$g13 (2017), 612-619$$pBeilstein J. Org. Chem.$$tBEILSTEIN JOURNAL OF ORGANIC CHEMISTRY$$x1860-5397
000061286 8564_ $$s361017$$uhttps://zaguan.unizar.es/record/61286/files/texto_completo.pdf$$yVersión publicada
000061286 8564_ $$s69885$$uhttps://zaguan.unizar.es/record/61286/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000061286 909CO $$ooai:zaguan.unizar.es:61286$$particulos$$pdriver
000061286 951__ $$a2021-09-30-08:25:35
000061286 980__ $$aARTICLE