000060632 001__ 60632
000060632 005__ 20210121114509.0
000060632 0247_ $$2doi$$a10.1021/om501274x
000060632 0248_ $$2sideral$$a89572
000060632 037__ $$aART-2015-89572
000060632 041__ $$aeng
000060632 100__ $$0(orcid)0000-0002-3284-1053$$aBuil, M.L.$$uUniversidad de Zaragoza
000060632 245__ $$aHydroboration and hydrogenation of an osmium-carbon triple bond: Osmium chemistry of a bis-s-borane
000060632 260__ $$c2015
000060632 5060_ $$aAccess copy available to the general public$$fUnrestricted
000060632 5203_ $$aThe complex [OsHCl(¿CPh)(IPr)(PiPr3)]OTf (1; IPr = 1,3-bis(2,6-iisopropylphenyl)imidazolylidene, OTf =CF3SO3) replaces the chloride ligand with a hydroxo group to give [OsH(OH)(¿CPh)(IPr)(PiPr3)]OTf (2), which undergoes hydroboration and hydrogenation of its metal-carbon triple bond. The hydroboration products depend upon the reagent used. Treatment of 2 with Na[BH4] leads to the bis-s-borane complex OsH2(¿2:¿2-H2BCH2Ph)(IPr)(PiPr3) (3), whereas pinacolborane (HBPin) affords the arene compound [Os(¿6-C6H5CH2Bpin)H(IPr)(PiPr3)]OTf (4). The hydrogenation of the triple bond of 2 occurs under 4 atm of H2 and yields the toluene derivative [Os(¿6-C6H5CH3)H(IPr)(PiPr3)]OTf (5).
000060632 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E35$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2011-23459$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2013-44303-P$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2014-51912-REDC
000060632 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000060632 590__ $$a4.186$$b2015
000060632 591__ $$aCHEMISTRY, ORGANIC$$b12 / 59 = 0.203$$c2015$$dQ1$$eT1
000060632 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b9 / 46 = 0.196$$c2015$$dQ1$$eT1
000060632 592__ $$a1.923$$b2015
000060632 593__ $$aInorganic Chemistry$$c2015$$dQ1
000060632 593__ $$aPhysical and Theoretical Chemistry$$c2015$$dQ1
000060632 593__ $$aOrganic Chemistry$$c2015$$dQ1
000060632 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000060632 700__ $$0(orcid)0000-0001-7620-9618$$aCardo, J.J.F.
000060632 700__ $$0(orcid)0000-0002-4829-7590$$aEsteruelas, M.A.
000060632 700__ $$aFernández, I.
000060632 700__ $$0(orcid)0000-0003-2094-719X$$aOñate, E.
000060632 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000060632 773__ $$g34, 3 (2015), 547-550$$pOrganometallics$$tOrganometallics$$x0276-7333
000060632 8564_ $$s575890$$uhttps://zaguan.unizar.es/record/60632/files/texto_completo.pdf$$yPostprint
000060632 8564_ $$s116517$$uhttps://zaguan.unizar.es/record/60632/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000060632 909CO $$ooai:zaguan.unizar.es:60632$$particulos$$pdriver
000060632 951__ $$a2021-01-21-10:55:48
000060632 980__ $$aARTICLE